Development of Alkylation Toluene with Methanol for Fuel on Modified ZSM-5 Zeolites by Amphoteric Surfactant

ZnO modified ZSM-5 and Y zeolites fabricated by atomic layer deposition for propane conversion.

ZnO modified ZSM-5 and Y zeolites are synthesized by performing atomic layer deposition (ALD) of ZnO to HZSM-5 and HY using diethyl zinc and water as the precursors. The surface area and pore volume of ZSM-5 and Y zeolites are progressively reduced with the increasing number of ZnO ALD cycles. XRD and SEM characterization methods show that highly dispersed ZnO species are deposited on the inter...

Zeolite catalyzed alkylation of toluene by alcohol

Vapor-phase methylation of toluene using methanol and its isopropylation with 2-propanol has been investigated ina down flow reactor under atmospheric conditions using N2 carrier over a series of surface modified andunmodified ZSM-5 (Si/Al= 60-170) loaded with H3PO4, differing in the external surface treatment of the zeolites.The feed molar ratios of toluene/methanol and toluene/2-propanol were...

Structure of toluene6.4-ZSM-5 and the toluene disproportionation reaction on ZSM-5.

The structure of a high-loading complex of ZSM-5 with 6.4 toluene molecules per unit cell has been determined by single-crystal X-ray diffraction. At least three kinds of toluene molecules were identified in the unit cell. Two disordered toluene molecules were located at the intersection of the straight and sinusoidal channels, the third in the sinusoidal channel. One (TOL1) of the two toluene ...

Dehydration of Methanol to Dimethyl Ether Employing Modified H-ZSM-5 Catalysts

Surfactant Modified Zeolites –adsorbents for Mycotoxins and Carriers of Drugs

The potential of surfactant modified zeolites as adsorbents for mycotoxins and as carrier of the pharmaceutical drugs was investigated. Ochratoxin A OCHRA (mycotoxin) and diclofenac sodium DS (anti-inflamatory drug) were used as model substances. Surface of the clinoptilolite was modified with different amounts of quaternary ammonium ions (hexadecyltrimethyl ammonium HDTMA or octadecyldimethylb...